منابع مشابه
Supraicosahedral ( metalla ) carboranes *
Although supraicosahedral (hetero)boranes have long been of interest to theoreticians, the area is under-developed from a synthetic viewpoint. The synthesis of supraicosahedral carboranes by reduction then capitation (RedCap) of C2B10 species is attractive, but unsuccessful as long as the cage carbon atoms are free to separate in the reduction step. Studies on 4,1,6-MC2B10 13-vertex metallacarb...
متن کاملThe medicinal chemistry of carboranes
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متن کاملPalladium-catalyzed selective fluorination of o-carboranes.
A Pd(II)-catalyzed direct selective fluorination reaction of carboranes using a F(+) reagent has been developed, leading to a series of polyfluorocarboranes in high isolated yields. The mechanism involving electrophilic B-H activation, oxidation of Pd(II) by F(+) species, and reductive elimination is proposed.
متن کاملCarboranes in the chemist's toolbox.
Once seldom encountered outside of a few laboratories, carboranes are now everywhere, playing a role in the development of a broad range of technologies encompassing organic synthesis, radionuclide handling, drug design, heat-resistant polymers, cancer therapy, nanomaterials, catalysis, metal-organic frameworks, molecular machines, batteries, electronic devices, and more. This perspective highl...
متن کاملRearrangements in icosahedral boranes and carboranes revisited
The structure, stability, and intermolecular rearrangements between ortho-, meta-, and para-C2B10H12 and were investigated using the hybrid density functional B3LYP/6-31G(d) for vibrational frequencies, as well as B3LYP/6-311+G(2d,p) for single-point electronic energies. The general trends in free energies of rearrangement between ortho-C2B10H12 to meta-C2B10H12 and meta-C2B10H12 to para-C2B10H...
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ژورنال
عنوان ژورنال: Materials Today
سال: 2009
ISSN: 1369-7021
DOI: 10.1016/s1369-7021(09)70150-6